stringtranslate.com

Isotopes of fluorine

Fluorine (9F) has 18 known isotopes ranging from 13
F
 to 31
F
 (with the exception of 30
F
) and two isomers (18m
F
 and 26m
F
). Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element.

The longest-lived radioisotope is 18F; it has a half-life of 109.734(8) min. All other fluorine isotopes have half-lives of less than a minute, and most of those less than a second. The least stable known isotope is 14
F
, whose half-life is 500(60) yoctoseconds,[4] corresponding to a resonance width of 910(100) keV.

List of isotopes

  1. ^ mF – Excited nuclear isomer.
  2. ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. ^ a b # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. ^ Modes of decay:
  6. ^ Bold symbol as daughter – Daughter product is stable.
  7. ^ ( ) spin value – Indicates spin with weak assignment arguments.
  8. ^ a b c d e f g h i j Decay mode shown is energetically allowed, but has not been experimentally observed to occur in this nuclide.
  9. ^ Intermediate product of various CNO cycles in stellar nucleosynthesis as part of the process producing helium from hydrogen
  10. ^ Has medicinal uses

Fluorine-18

Of the unstable nuclides of fluorine, 18
F
 has the longest half-life, 109.734(8) min. It decays to 18
O
 via β+ decay. For this reason 18
F
 is a commercially important source of positrons. Its major value is in the production of the radiopharmaceutical fludeoxyglucose, used in positron emission tomography in medicine.

Fluorine-18 is the lightest unstable nuclide with equal odd numbers of protons and neutrons, having 9 of each. (See also the "magic numbers" discussion of nuclide stability.)[7]

Fluorine-19

Fluorine-19 is the only stable isotope of fluorine. Its abundance is 100%; no other isotopes of fluorine exist in significant quantities. Its binding energy is 147801.3648(38) keV. Fluorine-19 is NMR-active with a spin of 1/2+, so it is used in fluorine-19 NMR spectroscopy.

Fluorine-20

Fluorine-20 is an unstable isotope of fluorine. It has a half-life of 11.0062(80) s and decays via beta decay to the stable nuclide 20
Ne
. Its specific radioactivity is 1.8693(14)×10+21 Bq/g and has a mean lifetime of 15.879(12) s.

Fluorine-21

Fluorine-21, as with fluorine-20, is also an unstable isotope of fluorine. It has a half-life of 4.158(20) s. It undergoes beta decay as well, decaying to 21
Ne
, which is a stable nuclide. Its specific activity is 4.781(23)×10+21 Bq/g.

Isomers

Only two nuclear isomers (long-lived excited nuclear states), fluorine-18m and fluorine-26m, have been characterized.[4] The half-life of 18m
F
 before it undergoes isomeric transition is 162(7) nanoseconds.[4] This is less than the decay half-life of any of the fluorine radioisotope nuclear ground states except for mass numbers 14–16, 28, and 31. [8] The half-life of 26m
F
 is 2.2(1) milliseconds; it decays mainly to its ground state of 26
F
 or (rarely, via beta-minus decay) to one of high excited states of 26
Ne
 with delayed neutron emission.[4]

External links

References

  1. ^ Chisté & Bé 2011.
  2. ^ "Standard Atomic Weights: Fluorine". CIAAW. 2021.
  3. ^ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN 1365-3075.
  4. ^ a b c d e f g Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  5. ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. ^ Charity, R. J. (2 April 2021). "Observation of the Exotic Isotope 13 F Located Four Neutrons beyond the Proton Drip Line". Physical Review Letters. 126 (13): 2501. Bibcode:2021PhRvL.126m2501C. doi:10.1103/PhysRevLett.126.132501. OSTI 1773500. PMID 33861136. S2CID 233259561. Retrieved 5 April 2021.
  7. ^ National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
  8. ^ Audi, G.; Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S. (2017). "The NUBASE2016 evaluation of nuclear properties" (PDF). Chinese Physics C. 41 (3): 030001. Bibcode:2017ChPhC..41c0001A. doi:10.1088/1674-1137/41/3/030001.

Sources