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Guluronic acid

Guluronic acid is a uronic acid monosaccharide that may be derived from gulose.[1] l-Guluronic acid is a C-3 epimer of l-galacturonic acid and a C-5 epimer of d-mannuronic acid.[2] Along with d-mannuronic acid, l-guluronic acid is a component of alginic acid, a polysaccharide found in brown algae.[3] α-L-Guluronic acid has been found to bind divalent metal ions (such as calcium and strontium) through the carboxylate moiety and through the axial-equatorial-axial arrangement of hydroxyl groups found around the ring.[4]

References

  1. ^ Oxford Dictionary of Biochemistry and Molecular Biology. Oxford University Press. 2006. ISBN 9780198529170. Retrieved 30 May 2021.
  2. ^ Zhu, Benwei; Yin, Heng (2015). "Alginate lyase: Review of major sources and classification, properties, structure-function analysis and applications". Bioengineered. 6 (3): 125–131. doi:10.1080/21655979.2015.1030543. PMC 4601208. PMID 25831216.
  3. ^ Gacesa, Peter (1992). "Enzymic degradation of alginates". International Journal of Biochemistry. 24 (4): 545–552. doi:10.1016/0020-711x(92)90325-u. PMID 1516726.
  4. ^ Rowbotham, Jack S.; Christopher Greenwell, H.; Dyer, Philip W. (2021). "Opening the Egg Box : NMR spectroscopic analysis of the interactions between s-block cations and kelp monosaccharides". Dalton Transactions. 50 (38): 13246–13255. doi:10.1039/D0DT04375C. ISSN 1477-9226. PMID 34617523.