X-ray notation

X-ray notation is a method of labeling atomic orbitals that grew out of X-ray science. Also known as IUPAC notation, it was adopted by the International Union of Pure and Applied Chemistry in 1991 as a simplification of the older Siegbahn notation.^[1] In X-ray notation, every principal quantum number is given a letter associated with it. In many areas of physics and chemistry, atomic orbitals are described with spectroscopic notation (1s, 2s, 2p, 3s, 3p, etc.), but the more traditional X-ray notation is still used with most X-ray spectroscopy techniques including AES and XPS.

Conversion

Uses

• X-ray sources are classified by the type of material and orbital used to generate them. For example, Cu_Kα X-rays are emitted from the K orbital of copper.
• X-ray absorption is reported as which orbital absorbed the x-ray photon. In EXAFS and XMCD the L-edge or the L absorption edge is the point where the L orbital begins to absorb x-rays.
• Auger peaks are identified with three orbital definitions, for example KL₁L₂. In this case, K represents the hole that is initially present at the core level, L₁ the initial state of the electron that relaxes down into the core level hole, and L₂ the initial energy state of the emitted electron.

See also

• Siegbahn notation for the names of spectral lines used in X-ray spectroscopy
• Spectroscopic notation
• Term symbol notation

References

1. R. JENKINS, R. MANNE, R. ROBIN and C. SENEMAUD (1991). "NOMENCLATURE SYSTEM FOR X-RAY SPECTROSCOPY" (PDF). IUPAC. Retrieved 10 May 2018.{{cite web}}: CS1 maint: multiple names: authors list (link)
2. Dr. Garrett's Class Notes page 12 http://www.cem.msu.edu/~cem924sg/Topic09.pdf Retrieved 10-07-08
3. IUPAC Table VIII.1 page 5 http://old.iupac.org/reports/V/spectro/partVIII.pdf Retrieved 30-05-09