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Trimethylstibine

Trimethylstibine is an organoantimony compound with the formula Sb(CH3)3. It is a colorless pyrophoric and toxic liquid.[2] It is synthesized by treatment of antimony trichloride and methyl Grignard reagent.[3] It is produced by anaerobic bacteria in antimony-rich soils.[4] In contrast to trimethylphosphine, trimethylstibine is a weaker Lewis base. It is used in the production of some III-V semiconductors.

References

  1. ^ "trimethylantimony - PubChem Public Chemical Database". The PubChem Project. USA: National Center for Biotechnology Information. 26 March 2005. Descriptors Computed from Structure. Retrieved 25 September 2011.
  2. ^ Wiberg, Nils; Wiberg, Egon; Holleman, A. F. (2001), Inorganic Chemistry, Academic Press, p. 766, ISBN 0-12-352651-5, retrieved 2009-07-17
  3. ^ Sabina C. Grund, Kunibert Hanusch, Hans J. Breunig, Hans Uwe Wolf "Antimony and Antimony Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, 2006, Wiley-VCH, Weinheim. doi:10.1002/14356007.a03_055.pub2
  4. ^ Craig, P. J. (2003), Organometallic Compounds in the Environment (2 ed.), Wiley and Sons, p. 295, ISBN 978-0-471-89993-8, retrieved 2009-07-17